Hybrid photocathode consisting of a CuGaO2 p-type semiconductor and a Ru(ii)–Re(i) supramolecular photocatalyst: non-biased visible-light-driven CO2 reduction with water oxidation† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c7sc00940b Click here for additional data file.

نویسندگان

  • Hiromu Kumagai
  • Go Sahara
  • Kazuhiko Maeda
  • Masanobu Higashi
  • Ryu Abe
  • Osamu Ishitani
چکیده

A CuGaO2 p-type semiconductor electrode was successfully employed for constructing a new hybrid photocathode with a Ru(II)–Re(I) supramolecular photocatalyst (RuRe/CuGaO2). The RuRe/CuGaO2 photocathode displayed photoelectrochemical activity for the conversion of CO2 to CO in an aqueous electrolyte solution with a positive onset potential of +0.3 V vs. Ag/AgCl, which is 0.4 V more positive in comparison to a previously reported hybrid photocathode that used a NiO electrode instead of CuGaO2. A photoelectrochemical cell comprising this RuRe/CuGaO2 photocathode and a CoOx/TaON photoanode enabled the visible-light-driven catalytic reduction of CO2 using water as a reductant to give CO and O2 without applying any external bias. This is the first self-driven photoelectrochemical cell constructed with the molecular photocatalyst to achieve the reduction of CO2 by only using visible light as the energy source and water as a reductant.

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Hybrid photocathode consisting of a CuGaO2 p-type semiconductor and a Ru(ii)-Re(i) supramolecular photocatalyst: non-biased visible-light-driven CO2 reduction with water oxidation.

A CuGaO2 p-type semiconductor electrode was successfully employed for constructing a new hybrid photocathode with a Ru(ii)-Re(i) supramolecular photocatalyst (RuRe/CuGaO2). The RuRe/CuGaO2 photocathode displayed photoelectrochemical activity for the conversion of CO2 to CO in an aqueous electrolyte solution with a positive onset potential of +0.3 V vs. Ag/AgCl, which is 0.4 V more positive in c...

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Rhenium(i) trinuclear rings as highly efficient redox photosensitizers for photocatalytic CO2 reduction† †Electronic supplementary information (ESI) available: Franck–Condon analysis; photochemical one-electron-reduced species formation and characterisation; photophysical, electrochemical and quenching properties of R(4·5) in DMA; photophysical and electrochemical properties of the catalysts; photocatalytic CO2 reduction experiments and additional data. See DOI: 10.1039/c6sc01913g Click here for additional data file.

We developed new cyclic Re(I)-based trinuclear redox photosensitizers with both high oxidation power in the excited state and strong reduction power in the reduced form. These excellent properties were achieved by introducing electron-donating groups on the diimine ligand of the Re(I) metal centre and by connecting each Re(I) unit with polyphenyl–bisphosphine bridging ligands. These Re-rings we...

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عنوان ژورنال:

دوره 8  شماره 

صفحات  -

تاریخ انتشار 2017